Addition of Sulfur-containing Silane Coupling Agents and Precipitated Silica to Tire Compound Formulations Aug 02, 2022

Silane coupling agent can improve the grip of the tire on the wet road surface, improve its puncture and tear strength, improve the heat resistance and chipping resistance, improve the resistance to ozone aging and cracking, and improve the resistance to Abrasiveness. Features, reduce friction and heat generation, reduce rolling resistance.

 

Tread Compound

(1) Passenger (radial) tread

Precipitated silica with the help of a coupling agent can improve wet grip and reduce rolling resistance. In oil-extended natural polybutadiene rubber tread compounds, when 14% precipitated silica was used instead of carbon black, road traction was improved by 5%, rolling resistance was reduced by 18%, and fuel consumption was reduced by 3%. The rolling resistance produced by the tread is 50% of the total rolling resistance of the tire. Since the tread compound has a great influence on the rolling resistance of the tire, it is particularly important to reduce the rolling resistance of the tread.

(2) In truck tire treads

With the help of coupling agents, precipitated silica can improve its puncture and tear resistance and reduce rolling resistance. In the tread of natural rubber truck tires, 30 parts of precipitated silica is used to replace carbon black, which improves the cutting resistance and crack resistance of the tread rubber, reduces the rolling resistance by 30%, and has more obvious high dispersion precipitation Effect silica. .

(3) In off-road tire treads

With the help of coupling agents, silica can improve heat resistance, chip resistance and tear strength. Replacing carbon black with 10 phr precipitated silica in NR and SBR treads also significantly improved heat, chip and tear resistance.

Bis [3-(triethoxysilyl) propyl] tetrasulfide,Bis(3-triethoxysilylpropyl)disulfane,Thiocyanicacid,3-(triethoxysilyl) propylester,Mono Sulfur Silane,3-(triethoxysilyl)propanethiol,3-Mercaptopropylmethyldimethoxysilane,3-Mercaptopropyltriethoxysilane

Sidewall Rubber

In sidewall rubber, silica can improve ozone aging resistance, crack resistance and cut resistance through the action of coupling agent.

SiO2, Precipitated Silica, White Carbon, Silicon Dioxide, Conventional Silica Powder, Amorphous Precipitated Silica

Sulfur Silane Coupling Agent Crosile for Rubber Type and Filler Modified
Product Type Chemical Name CAS NO Purity Application
Crosile®69 Bis [3-(triethoxysilyl) propyl] tetrasulfide 40372-72-3 22% Sulfur Conc Rubber, tyre
Crosile®75 Bis(3-triethoxysilylpropyl)disulfane 56706-10-6 15% Sulfur Conc
Crosile®264 Thiocyanicacid,3-(triethoxysilyl) propylester 34708-08-2 ≥96% 
Crosile®966 Mono Sulfur Silane N.A. ≥97%
Crosile®963 3-(triethoxysilyl)propanethiol N.A. 3.3% Sulfur Conc
Crosile®970 3-Mercaptopropylmethyldimethoxysilane 31001-77-1 ≥98%
Crosile®1891 3-Mercaptopropyltriethoxysilane 14814-09-6 ≥97% Filler Modified, rubber, Silicone oil modifier, sealant
Crosile®189 3-Mercaptopropyltrimethoxysilane 4420-74-0 ≥97%

 

White Filter Powder Precipitated Silica for Rubber

Series Product Code Surface Area
(BET) m2/g
Application Memo

Easily Dispersed Precipitated Silica 

(Foot Wear, Tire, Rubber Goods)

ZC−195P or ZC−195GR 175 −205 Rubber Reinforcing Filler: High reinforcing potential and imparts to rubber compounds particularly high shore hardness, tensile strength, tear resistance and abrasion resistance.
ZC−185P or ZC−185GR 165 −195
ZC−185MP 165 −195
ZC−175P or ZC−175GR 155 −185
ZC−165P or ZC−165GR 145−175
ZC−120P or ZC−120GR 105−135

Highly Dispersible Silica 

(Tire)

ZC−165HD (Granular) 145−175 Highly dispersion silica: Better wet−side resistance than general silica. Low rolling−resistance, low heat buildup Excellent abrasive resistance, tear resistance
ZC−165MP (Mico pearl) 145−175
ZC−120MP  105−135

SAI Series Silica

(Silicone Rubber)

SAI−779 130-160 Super ting precipitated silica used in high quality silicone rubber with excellent anti−yellow.
SAI−779-1 150-180
SAI−800 150-180

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